![]() If you believe that any review contained on our site infringes upon your copyright, please email us. All submitted reviews become the licensed property of Sheet Music Plus and are subject to all laws pertaining thereto.If you have any suggestions or comments on the guidelines, please email us. We cannot post your review if it violates these guidelines. ![]()
0 Comments
![]() Ionic radius is a measure of an atoms ion in a crystal lattice and which is a half distance between two ions that are barely touching each other. ls = low spin, hs= high spin.24 Why is the ionic radius of Na+ less than F? What is atomic radius and ionic radius?Ītomic radius is defined as a distance from the center of the nucleus to the outermost shell containing the electrons. This is because the greater covalent character of the bonds in AgCl and AgBr reduces the bond length and hence the apparent ionic radius of Ag +, an effect which is not present in the halides of the more electropositive sodium, nor in silver fluoride in which the fluoride ion is relatively unpolarizable. On the basis of the fluorides, one would say that Ag + is larger than Na +, but on the basis of the chlorides and bromides the opposite appears to be true. This is illustrated by the unit cell parameters for sodium and silver halides in the table. No bond is completely ionic, and some supposedly "ionic" compounds, especially of the transition metals, are particularly covalent in character. ![]() All compounds crystallize in the NaCl structure.Īn "anomalous" ionic radius in a crystal is often a sign of significant covalent character in the bonding. ![]() Unit cell parameters (in pm, equal to two M–X bond lengths) for sodium and silver halides. In general, ionic radius decreases with increasing positive charge and increases with increasing negative charge. Anions (negatively charged) are almost invariable larger than cations (positively charged), although the fluorides of some alkali metals are rare exceptions. ![]() Ionic size (for the same ion) also increases with increasing coordination number, and an ion in a high-spin state will be larger than the same ion in a low-spin state. As with other types of atomic radius, ionic radii increase on descending a group. Nevertheless, ionic radius values are sufficiently transferable to allow periodic trends to be recognized. The ionic radius is not a fixed property of a given ion, but varies with coordination number, spin state and other parameters. The latter values are thought to be a more accurate approximation to the "true" relative sizes of anions and cations in ionic crystals. Some sources have retained Pauling's reference of r ion(O 2−) = 140 pm, while other sources prefer to list "effective" ionic radii based on r ion(O 2−) = 126 pm. Ī major review of crystallographic data led to the publication of a revised set of ionic radii in 1976, and these are preferred to Pauling's original values. By comparing many different compounds, and with a certain amount of chemical intuition, Pauling decided to assign a radius of 140 pm to the oxide ion O 2−, at which point he was able to calculate the radii of the other ions by subtraction. However, it is not apparent what proportion of this distance is due to the size of the sodium ion and what proportion is due to the size of the chloride ion. For example, it can be readily determined that each side of the unit cell of sodium chloride is 564.02 pm in length, and that this length is twice the distance between the centre of a sodium ion and the centre of a chloride ion:Ģ = 564.02 pm X-ray crystallography can readily give the length of the side of the unit cell of a crystal, but it is much more difficult (in most cases impossible, even with more modern techniques) to distinguish a boundary between two ions. The concept of ionic radius was developed independently by Goldschmidt and Pauling in the 1920s to summarize the data being generated by the (then) new technique of X-ray crystallography: it is Pauling's approach which proved to be the more influential. Better weighing performance in 6 easy steps Should they upgrade their already solid controller to the new version or, if they don’t own it already, should they even spend their money on the new version when they can now get the original for less.Ī note about the S2 and S4 reviews - these are going to be more than update announcements. This direction, embraced by many hardware manufacturers lately, puts consumers in a very difficult position. While the S2 MK2 is just an update of their solid Kontrol S2, it does provide a few extra tweaks to the design and featureset. Their controllers, all-in-one solutions like the Kontrol S2 MK2 and modular products like the Kontrol Z1, always boast extremely tight integration and super high quality hardware. Native Instruments has an inherent advantage in their hardware design: they also design the software. In a world of me-too controllers, a world where almost every controller on the market looks identical, manufacturers need to dig deep to set themselves apart. Powered via USB 2.Link: NI | Price: $499/€449/£379 (offer price) | Manual: PDF Introduction.Headphone out (1/8" / 3.5 mm TRS), 2x stereo main out (line and 1/8" / 3.5 mm TRS).Connectivity:44.1/48 kHz / 24-bit audio interface.Pro Mixer Layout with redesigned monitoring section and four dedicated slots for Mixer FX plus filters.Choose from eight FX and three filter types to assign to four hardware FX slots.New Mixer FX for instant one-knob FX and filter control on each channel.3-band EQswith modelling of industry standard mixer EQs.16 RGB pads for triggering Hotcues, loops, or samples.club-standard layout with identical deck design, 2-channel mixer, and fast control of key Traktor features.Beatgrid adjust mode: Use the jog wheel to manually adjust beatgrid in Traktor.Jog mode:Classic spin-to-nudge function, as well as scratch capability.New large (14 cm/5.5") smooth precision jog wheels with two modes.Choose from eight club-grade effects and three filters, and use up to four at a time with the dedicated Mixer FX control. Open up a big reverb, a dubby delay, or a smooth filter to get your tracks popping during the mix. Build exciting transitions with one-touch control of new Mixer FX on each channel. You’ve got the perfect playlist down, but it’s what goes on between your tracks that can make all the difference. Everything will always be in sync with the beat, so you’ll never lose the groove. Use loops for longer mixes or for more time to experiment. Because each is assigned to one of eight pads on each deck, you can play them like an instrument to seriously chop things up. Jump to different parts of a track with cue points, depending on what the crowd needs. Because they’re bigger, nudging, scratching, and scrolling is even easier. Use it to beatmatch tracks – nudge the deck forward or back with the jog wheels to get a track in sync, use the touch-sensitive top-plate to find your starting position, or even spin it back for high-energy rewinds. If your style is very hands-on, Native Instruments have given you a lot of jog wheel to play with. Get the sound in your head through the speakers in seconds. Easily access expressive effects and essential controls for chops, stops, and seamless transitions. Get your mixes down super-quick: Line up your next track, find the cue point, cut the kick, and bring in some reverb before the drop. Whether you’re at a house party, a bar, or the club, you can create mixes made to make you move. You can leave the beatmatching to Traktor, so you have more time to pick tunes that fit the vibe, experiment with FX, use looping and remix decks, and to define your own sound. Plug in, line up a few of your favourite tracks, and get mixing wherever you are. Turn the music you listen to into the sets you play, with a streamlined interface that makes blending tracks a breeze. Craft sets on two decks and get creative with easy-to-use tools like looping, beat syncing, and club-grade effects. ![]() Whether it’s bass-heavy breakdowns, steppy synths, or peak-time rewinds that define your style, the Traktor Kontrol S2 has everything you need to make your mix happen. ![]()
![]() I told them that they could use whichever method they preferred, once they had tried both methods. This method made more sense to a lot of kids. Every Day Math was the name of the program that the elementary schools adopted that uses the lattice method to teach multiplication. Most-not all.Ī few years ago, when the 'every day math' kids made it to the high school, I added this method to my algebra classes. ![]() Pic 5 This was my go to method for a lot of years. Now they must put in the appropriate plus signs to separate the terms. Then you draw your equal sign (line under all your work so far) any you add the columns. Make sure that 'like' terms are always lined up properly. Pic 3 and 4 Repeat this process for each term of the bottom polynomial if there are more terms. This feels 'normal' to those of us that grew up on this method of multiplication. When they multiply the second term on the bottom by the second term of the top, they will probably find that they need to place it just to the left of the previous term. This marks where they should place the new term they just found. Before you have students write it down, have them look at the first row of their answer. Multiply it by the right hand term of the top. Pic 2 When that row is complete, move to the next term to the left on the bottom polynomial. I have found that kids will insert appropriate minus signs but usually forget the plus signs. Make sure to leave a space between terms (or have the kids insert a + or - sign). Start on the right hand side only because that is where order we learned as kids. Pic #1 Multiply the bottom right term by each individual term of the polynomial above it. Line up the terms like you would if they were just individual numbers. Write the longer (more terms) polynomial on top with the shorter one under it. This method works well for polynomial multiplication. ![]() I still go back to the traditional method that I learned first. In college, I actually learned 5 or 6 other method of multiplying. The middle school teachers tried to un-teach it-to varying degrees of success. My son's were taught the 'lattice' method so I know some people learned different methods first. When most of us were in school, we were taught the same method of multiplying 2 numbers. Then the kids can extrapolate their skills back to the simpler binomial problems. I prefer to work on the higher order problems first. I would not even acknowledge the mnemonic except that the kids have all heard of it before they get to me. It does not have enough letters in the name to allow it to be used as a mnemonic for trinomials or beyond. The kids memorize a procedure-the favorite method around here is F.O.I.L.-and they practice it. Then as an after thought throw in a few higher order problems and expect the kids to extrapolate knowledge that they don't really have. (Some just have made no sense to me so I cannot say that I have actually learned them all.) The problem, as I see it, is that we (math teachers) keep teaching binomial (only 2 terms) multiplication for days on end first. I have made it my goal to learn as many of the methods that I could. Teachers all have their favorite methods of teaching the process. ![]() I have taught math for many years (too many?) and one thing that I have found over the years is that kids have trouble multiplying higher order polynomials. ![]() thredUP will swap its millionth item this month and is now adding over 1,000 moms a day. This new funding comes just one year after thredUP’s launch and significant company milestones. Tim Haley of Redpoint Ventures will join Patricia Nakache on the thredUP board. Redpoint Ventures led the round with Trinity Ventures and former eBay CEO Brian Swette participating. San Francisco, CA – thredUP Inc, the nation’s leading online platform for swapping kids clothes, toys and books, today announced that it has completed a series B round of funding, bringing total committed capital to $8.7M. ThredUP Adds $7M Series B round to support rapid user growth ThredUP is part of a trend toward what some call “the sharing economy” or “collaborative consumption,” along with other companies like AirBnB and RelayRides. The San Francisco-based company says it will soon swap its millionth item. Then they list them on thredUP for another family to claim, which pays $5 plus $10.95 shipping. ThredUP works by sending USPS flat-rate boxes out to its members, who fill them with clothes for kids of the same size, gender and season. I will definitely be browsing the site again, and I may even try their ‘ Clean Out – Cash In‘ program which pays me to send in my ‘like-new’ kids clothes for $$! (either store credit or PayPal Payout) Plus, they pay for shipping both ways!.ThredUP, the kids’ clothing exchange site, has raised $7 million in Series B funding from Redpoint Ventures, Trinity Ventures and Brian Swette. But if something should slip pass their quality control, they will refund you the cost and ship it to you any way! I was beyond impressed, since I probably wouldn’t have even noticed the flaw if they hadn’t pointed it out. ![]() Here’s the icing on the cake… Do you see that little pink sticker on the Mets Jersey near the top of the ‘M’?Īpparently, there was some slight wear on this Jersey that slipped past their quality control – so they completely REFUNDED me the cost of that Jersey!! Which brought my total down to $3.34 for the whole order!!! ThredUp’s policy is to never accept used clothing that has any signs of wear on it. Plus I have an extra $10 credit to spend next time! The total after I applied my $10 coupon & promo code was $7.74 – and that included shipping! (shipping is normally a $6.95 flat rate or Free for anything over $40). I found these 3 Sports Jerseys for my 3 boys (which are usually VERY expensive) and threw them into my cart. I signed up using this link… which gave me $10 off my first & second orders – which could even be used towards shipping costs! The link & $20 promo should still work, so feel free to try it yourself! =) Plus, right now, there is an additional 20% off your order (stackable with the $10 credit) – Just use code AUGUST20 for the extra discount! I love thrift stores, and the concept of ‘thrifting’ online for clothes was too cool to pass up! Plus, you can BOTH buy your clothes from them, AND sell your ‘like-new’ clothes back to them! Think of it like eBay, but without the hassle. Last week, I had a friend tell me about a new company called “ ” If you haven’t heard of them, they are basically a high-end / high-quality thrift store for kids clothing online. It was delivered via UPS and it contained 3 Name Brand Sports Jerseys for my boys… and it only cost $3.34 – including shipping! Crazy right? I know! Here’s the scoop on how I did it. This was too good not to share with you guys… I just got this package in the mail today. ![]() UPDATE 2/2014: ThredUp now carries clothes for women too! I recently got a package with 3 items from them and I loved everything! And it only cost me $8! READ MY LATEST REVIEW HERE. ![]() … How Are You Feeling Today With O Kokichi Ouma Memes Danganronpa Amino Meme On Me Me.|Kokichi ouma worshippers only| x reader wattpad Robot x reader wattpad Kokichi ouma x reader lemon Wattpad … Contests Mini Frights Memes Interactive Community Freddy Fazbear’s Pizza …Funny memes can drive organic traffic to your website. According to Dictionnaire Infernal – Collin de …Kokichi truyện SAIOUMA ONE SHOTS … This is a place to share all your fanarts, fanfic, cosplay, memes and anything …This visual is about drv3 kokichi manga kokichiouma freetoedit #drv3 … #drv3 killing harmony #killing harmony #wholesome memes #wholesome #manga edit …Buy Rantaro Amami Plushie, Saihara Shuichi Plush, Ouma Kokichi Anime Plushies, … #gaming #danganronpa #danganronpa2 #danganronpav3 #ifunny #stupud #meme.This item: Rantaro Amami Plushie, Saihara Shuichi Plush, Ouma Kokichi Anime Plushies, Momota Kaito … Ifunny is stupud – popular memes on the site iFunny…. Listed on Jan 15, 2023.Hot picture Kokichi Ouma Meme, find more porn picture kokichi ouma by dailydraw noaa, pin on danganronpa, roblox kokichi ouma roblox lumber tycoon xbox one … – Explore Kokichi Ouma’s board “Alastor meme” on Pinterest.
![]() This cool little hidden spot is the birthplace of UPS. It is refreshing and you will forget how you are to the city Go get lunch somewhere as take-out and bring it to this park to eat. for a minute or an hour.Īmazing location a great *secret* place we went to get some sandwiches in Salumi close by and enjoyed eating them in this park, there are lots of small cute seating spaces and very quiet in the middle of seattleĪ good place to go to relax and listen to the nature in a big city and the mist off the waterfall feels good on a hot day and its never very busy great for romanceīeautiful park, however, Google incorrectly describes as "Monument to US Postal Workers" when in fact it was built to honor the employees of United Parcel Service. Its still one of the more beautiful spots, in a city already greatly over endowed with beautiful spots, to pause and catch your breath. It may be tiny, it may be more garden than park but. In the summer there are a few too many tourists, and the chairs are not that comfortable, so bring a cushion if you plan to sit for more than an hour. Grab a bite to go from one of the nearby restaurants, take a seat, and just relax in an environment made for just that purpose.Ī nice little getaway in the neighborhood where you can bring a book and chill out. This is a nice little vacation from the surrounding historic district low-end-of-downtown buzz that permeates the area. You wont find a better lunch spot in the area. It has a few trash cans and its a nice place to cool down in the summers. There is a security officer here and the transient mobs from Pioneer Square wont hassle you for money while you eat your lunch. Grab some lunch from one of the food trucks in Occidental Park, make the walk to this spot, and enjoy one of the most tranquil places in this chaotic city. Even most that live in Seattle dont know about this place. Now location hasa tiny waterfall park on the site of the company’s original location in Seattle remembering the shipping giant’s Original Starting location. Today it is now called United Parcel Service (UPS). If you happen by during the day, ok, but dont plan on going there late in the evenings.Īt this location in 1907, a young businessman borrowed $100 from a friend and started the American Messenger Company in Seattle, Washington. Oddly enough, int the warm summer days, when its dark till 10pm, this park can close up and shut down the water falls, and lock the iron gates at 5pm. Its not a public park but a site owned by a non-profit, so they close it and lock it up. But that doesnt matter, because its a beautiful little park filled with waterfalls! If we had more time, its a place I wouldnt mind staying for half a day in quiet comtemplation. Its walled off so you cant even tell that its there unless you peer through the thick plants of the trellis. Such a hidden gem in the middle of the city. Its also worth noting that on site security was visible there so it seems like during business hours its a pretty safe place to be. One of Seattles Diamonds in the Rough IMO. It smells a bit funky due to the water everywhere but is very beautiful year round. If I worked in this area I would eat my lunch here frequently. Just discovered this place, its beautiful and hidden near Pioneer Square. Its a monument to the people of UPS and not the USPS. ***ALSO, please someone correct the Google intro. With a simple idea, "A fast reliable small parcel delivery service." I found it very insightful that a hugely successfulīusiness like UPS could have begun at this Seattle location ![]() Invigorating in the midst of an urban landscape. The ionization of the water vapors are refreshingly I first visited this small waterfall park in the late 1970s. Today UPS spans the globe and generated over $58 billion in revenue. ![]() Jim Casey and Claude Ryan started "American Messenger Company" in the basement of Claudes uncles saloon, with $100 (what today would be about $2500). Thats because this is the sight one which that great company started August 28, 1907. One reviewer commented that oddly its run by UPS. Built in 1977 by Jim Casey, founder of UPS. Fantastically beautiful and peaceful little park in Pioneer Square, Seattle. ![]() “For me, ease of use is the most important feature in any tool. Infinity to-do list app offers multiple views-including Table, Columns, List, Calendar, Gantt, Chart and Form-that allow you to see your data from a different angle, as well as filter, group, and customize options to display it in a way that makes the most sense. Infinity lets you build customizable frameworks and processes using an unlimited number of boards within your workspace and structuring each board to follow your data flow. There are 23 attributes to add to your items, such as date, labels, text, checkboxes, formulas, and attachments. To avoid clutter, you can organize items within your workspace into folders, subfolders, and tabs. From simple checklists to large company projects, Infinity’s flexible structure allows you to create and scale tasks with ease. Infinity takes care of your tasks so you can become more productive. Infinity - A Versatile Checklist App for Personal and Business Use Now that we've got that out of the way, let's move on to the actual list! Best 20 To-Do List Apps to Use in 2023 1. We have included the pricing for each app so you can get the best for your money’s worth. Pricing-You don’t need a paid to-do list app to plan a party, but most of these tools have very basic features unless you choose a paid plan.Some to-do list apps on this list don’t have live support, so consider that you may have to rely on email support that can take days. Tech Support-If you get stuck or experience any issues, it’s essential to have great support.Additional Features-What devices does the app support? Are there integrations with other software? How can you organize tasks, and can you break them into smaller items?.Collaboration-If you are looking for a to-do list tracker for work, make sure that you pick an app that has collaboration tools such as task assigning, live chat, messaging, etc.Ease of Use-What is the interface like? Is it easy to create and manage tasks, or does it take a while for you to get used to the app?.Some checklist apps offer advanced productivity options like the Pomodoro timer. Productivity-Perform a weekly review of your tasks, use task visualization, and track your progress to understand how productive you really are.To-do list apps have reminders and alerts to keep you from missing a deadline or forgetting about a task you created. Time Management- Never miss an important task again.What can to-do list apps help you with? There are many ways these tools can make your daily life easier, and these are just a few. Compare features and prices and find the best app to manage your to-do lists. ![]() ![]() Occasionally, our brains tend to let us down when it comes to remembering birthdays or chores, so why not let a checklist app do the hard work of keeping track of things? We have reviewed 20 best to-do list apps to consider using in 2023, including free and paid software. 1 teaspoon baking powder – ¼ teaspoon baking soda + ½ teaspoon cream of tartar (for best results, bake immediately after batter is made).While they technically can be swapped out for each other, a few more additions are needed to insure they work correctly. Baking powder, on the other hand, already contains its own acid and does not need to be activated. They both help your baked goods to rise, however, baking soda needs to be activated by another acidic ingredient. Vegetable shortening – equal parts butter or margarine (if using margarine, remove ½ teaspoon salt per cup of margarine from the recipe)īaking Powder, Cream of Tartar and Baking Soda Substitutesĭespite sounding similar, baking powder and baking soda are very different ingredients.In most cases, you can also use coconut or olive oil in place of vegetable oil however, keep in mind that those oils have very distinct flavors and my come through in your recipe. Vegetable oil – equal parts melted butter, melted vegetable shortening, applesauce or fruit puree.If you only have salted butter on hand, remove ½ teaspoon of salt from the recipe per 1 cup of salted butter. If your recipe calls for salted butter, you can use unsalted butter and add ½ teaspoon of salt per 1 cup of butter. Salted and unsalted butter are easily interchangeable, just tweak the amount of salt you add. For melted butter, use equal parts oil or melted vegetable shortening.If you don’t have butter (room temperature), use equal parts solid vegetable shortening.For room temperature butter, you can use vegetable shortening or margarine. For example, if you need to replace oil, use melted butter. However, it’s a good idea to keep the fat in the state the recipe calls for, since liquid fats tend to produce a denser crumb. Butter can be used in place of oil and visa versa. ![]() ![]() ![]() The good thing about fats is that you can generally swap one out for the other. |
AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |